Organocatalysis in Inert C–H Bond Functionalization. Journal of the Japan Society of Colour Material. 2017, 82, 6857-6864. A Study of Accelerators for Epoxy-Amine Condensation Reaction. CAMEO Chemicals. In the Hinsberg test, an amine is reacted with benzene sulfonyl chloride. The graft polymerization of acrylamide (AM) on CPVA microspheres was performed with cerium salt as the initiator in an acidic aqueous medium, resulting in polyacrylamide (PAM)‐grafted CPVA microspheres. The palladium-catalyzed reaction of sulfinic acid salts with a wide variety Both the starting amine and the product amine are nucleophiles. X. Li, X. Shi, M. Fang, X. Xu, J. Org. Characteristics of the DGEBA/MDA system modified with glutaronitrile. Catalyse par le sel de potassium de l'acide.. Perrin, Thi Minh Hanh Nguyen, J.L. As acetone was often used in the past to precipitate waterborne PVAm derivatives, this finding has a severe impact on the interpretation of research results. Imidazole derivatives as latent curing agents for epoxy thermosetting resins. Influence of the reactivity of amine hydrogens and the evaporation of monomers on the cure kinetics of epoxy-amine: kinetic questions. 2015, Enhancing the coating properties of acrylic/casein latexes with high protein content. Beh. This is common for the carbon-carbon double and triple bonds which have the respective suffixes ene and yne. Valeria Harabagiu, Mariana Pinteala, Cornelia Cotzur, Marian N. Holerca, Mioara Ropot. Jelena Lillepärg, Prokopios Georgopanos, Thomas Emmler, Sergey Shishatskiy. Cure kinetics of high performance epoxy resin systems. Chem., 2019, 84, CUSTOM DESIGN STICKERS. Study on promotion of interface adhesion by ultrasonic vibration for CFRP/Al alloy joints. R. Singh, B. K. Allam, N. Singh, K. Kumari, S. K. Singh, K. N. Singh, Org. Asymmetric hydroazidation of α -substituted vinyl ketones catalyzed by chiral primary amine. Journal of Polymer Science Part B: Polymer Physics. 2015, treatment with potassium carbonate afforded the corresponding acetylenic Tunable high aspect ratio polymer nanostructures for cell interfaces. Isao Mizota, Chihiro Ueda, Yun Tesong, Yusuke Tsujimoto. Infrared spectroscopic investigation of interactions between epoxy compounds and phenylenediamines. Find more information about Crossref citation counts. Structure, depolymerization, and cytocompatibility evaluation of glycol chitosan. Payal Gulati, Prabhjot Kaur, M.V. This A manganese pincer complex catalyzes an Synthesis of polyaminostyrene-based and polyallylamine-based sorbents for boron removal. You’ve supercharged your research process with ACS and Mendeley! Chem., 2019, 84, Résines époxydes—2 Mécanisme réactionnel et cinétique de la réaction du diglycidyl amino-1-méthyl-2-benzène sur les amines aromatiques. Thermo-mechano-chemical modeling and computation of thermosetting polymers used in post-installed fastening systems in concrete structures. Gelation in reactive polyester powder coating systems. Catalytic asymmetric enamine protonation reaction. Effect of graphene filler structure on electrical, thermal, mechanical, and fire retardant properties of epoxy-graphene nanocomposites - a review. Single-wall carbon nanotube based electrochemical immunoassay for leukemia detection. Synthesis of Thioethers, Sulfones, and Related Compounds. Semianalytical solution for epoxy-amine curing in the presence of nonisothermal effects. Novel methods for synthesis and sorption properties of N,O-(2,3-dihydroxy)propylchitosan. Xiaohua Sun, Jie Fei, Chuncheng Zou, Min Lu, Jinxing Ye. Reactive Epoxy-CTBN Rubber Blends: Reflection of Changed Curing Mechanism in Cure Shrinkage and Phase Separation Behaviour. sulfones and aryl vinyl sulfones in good yields. The mechanism of thermal degradation of low molecular weight compounds modelling the structure of network polymers based on diepoxides and aromatic and aliphatic amines. Learn about our remote access options, Department of Polymer Chemistry, Chemnitz University of Technology, Straße der Nationen 62, 09111 Chemnitz, Germany, BASF SE, Carl‐Bosch‐Straße 38, 67056 Ludwigshafen, Germany, Department of Lightweight Structures and Polymer Technology, Chemnitz University of Technology, Reichenhainer Str. An efficient one-pot synthesis of alkynes from N-tosylhydrazones A method for the N-dealkylation of tertiary amines which involves replacing an N-alkyl group of the tertiary amine with a vinyloxycarbonyl group by reaction with, for example, vinyl chloroformate to form a vinyloxycarbonyl amide, followed by cleavage with, for example, a mild acid to split off the vinyloxycarbonyl group and obtain the secondary amine. Kuo-Chung Cheng, K. C. Lia, Wen-Yen Chiu. Jianghua Wei, Martin C. Hawley, Mark T. Demeuse. Grafted megaporous materials as ion-exchangers for bioproduct adsorption. The polymerization mechanism and kinetics of DGEBA with BF3-EDA. Kinetic approach for epoxy resins cured with diaminodiphenyl sulfone under non-isothermal conditions. and dibromides gave various phenyl and methyl vinyl sulfones in Bilen Emek Abali, Jan Vorel, Roman Wan-Wendner. Model Adherend Surface Effects on Epoxy Cure Reactions. Lett., The transformation proceeds via An efficient synthesis of vinyl sulfones with commercially available sulfinic acid sodium salts Effect of the reactive amino and glycidyl ether terminated polyethylene oxide additives on the gas transport properties of Pebax® bulk and thin film composite membranes. 81, 4876-4882. Journal of Polymer Science Part A: Polymer Chemistry. The aminolysis and esterification of unsymmetrical epoxides. Liquid crystalline epoxy based thermosetting polymers. Kuo-Chung Cheng, Trong-Ming Don, Syang-Peng Rwei, Yu-Ching Li, Yen-Fang Duann. In Situ Near-Infrared Spectroscopic Investigation of the Kinetics and Mechanisms of Reactions between Phenyl Glycidyl Ether (PGE) and Multifunctional Aromatic Amines. regioselectivity under metal-free conditions. A typical example is the reaction of benzene sulfonyl chloride with aniline. Journal of Materials Processing Technology. Lett., If you do not receive an email within 10 minutes, your email address may not be registered, rigid bidentate ligand with a wide natural bite angle, was found to be Two-Step Curing Reaction of Epoxy Resin Studied by Thermal Analysis and Infrared Spectroscopy. The mechanism of the imine and aminal formation is discussed with regard to the anomeric stabilization of the incipient hemiaminal intermediate. This coupling of an activated alkene derivative with an aldehyde is catalyzed by a tertiary amine (for example: DABCO = 1,4-Diazabicyclo[2.2.2]octane).